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How to MOVE/COPY Windows SBS Server 2008 Shared User Folder
How to manually move shared folders
how to migrate users profile from one drive to another.

Firstly: First Lock shared folder.

Robocopy C:USERS_SHARED D:NEW_LOCATION /COPYALL /MIR /DCOPY:T /E /R:0

or

Robocopy C:USERS_SHARED D:NEW_LOCATION /COPY:DATSOU /MIR /DCOPY:T /E /R:0

Copy directory recursively (/E)
copy all file information (/COPYALL)
/COPY:DATSOU, D=Data, A=Attributes, T=Timestamps, S=Security=NTFS ACLs, O=Owner info, U=aUditing info)
do not retry locked files (/R:0)
(the number of retries on failed copies default value is 1 million)
preserve original directories’ Timestamps (/DCOPY:T)

This will definately work “saying” to Copy folder/files, timestamp, permisions and all. However, it is not yet tested if all of roaming profile will be working or not.

(You can find detailed Ref: http://technet.microsoft.com/en-us/library/cc733145%28WS.10%29.aspx)
And (http://technet.microsoft.com/en-us/library/cc875789%28v=ws.10%29.aspx)